Nuclear fuel

"Fuel rod" redirects here. Not to be confused with FuelRod.

Nuclear fuel process

A graph comparing nucleon number against binding energy

Close-up of a replica of the core of the research reactor at the Institut Laue-Langevin

Nuclear fuel refers to any substance, typically fissile material, which is used by nuclear power stations or other nuclear devices to generate energy.

Oxide fuel

For fission reactors, the fuel (typically based on uranium) is usually based on the metal oxide; the oxides are used rather than the metals themselves because the oxide melting point is much higher than that of the metal and because it cannot burn, being already in the oxidized state.

The thermal conductivity of zirconium metal and uranium dioxide as a function of temperature

Uranium dioxide

Uranium dioxide is a black semiconducting solid. It can be made by heating uranyl nitrate to form UO
₂.

UO₂(NO₃)₂ · 6 H₂O → UO₂ + 2 NO₂ + ½ O₂ + 6 H₂O (g)

This is then converted by heating with hydrogen to form UO₂. It can be made from enriched uranium hexafluoride by reacting with ammonia to form a solid called ammonium diuranate, (NH₄)₂U₂O₇. This is then heated (calcined) to form UO
₃ and U₃O₈ which is then converted by heating with hydrogen or ammonia to form UO₂. The UO₂ is mixed with an organic binder and pressed into pellets. The pellets are then fired at a much higher temperature (in hydrogen or argon) to sinter the solid. The aim is to form a dense solid which has few pores.

The thermal conductivity of uranium dioxide is very low compared with that of zirconium metal, and it goes down as the temperature goes up. Corrosion of uranium dioxide in water is controlled by similar electrochemical processes to the galvanic corrosion of a metal surface.

While exposed to the neutron flux during normal operation in the core environment, a small percentage of the ²³⁸U in the fuel absorbs excess neutrons and is transmuted into ²³⁹U. ²³⁹U rapidly decays into ²³⁹Np which in turn rapidly decays into ²³⁹Pu. The small percentage of ²³⁹Pu has a higher neutron cross section than ²³⁵U. As the ²³⁹Pu accumulates the chain reaction shifts from pure ²³⁵U at initiation of the fuel use to a ratio of about 70% ²³⁵U and 30% ²³⁹Pu at the end of the 18 to 24 month fuel exposure period.

MOX

Main article: MOX fuel

Mixed oxide, or MOX fuel, is a blend of plutonium and natural or depleted uranium which behaves similarly (though not identically) to the enriched uranium feed for which most nuclear reactors were designed. MOX fuel is an alternative to low enriched uranium (LEU) fuel used in the light water reactors which predominate nuclear power generation.

Some concern has been expressed that used MOX cores will introduce new disposal challenges, though MOX is a means to dispose of surplus plutonium by transmutation. Reprocessing of commercial nuclear fuel to make MOX was done in the Sellafield MOX Plant (England). As of 2015, MOX fuel is made in France at the Marcoule Nuclear Site, and to a lesser extent in Russia at the Mining and Chemical Combine, India and Japan. China plans to develop fast breeder reactors and reprocessing.

The Global Nuclear Energy Partnership was a U.S. proposal in the George W. Bush administration to form an international partnership to see spent nuclear fuel reprocessed in a way that renders the plutonium in it usable for nuclear fuel but not for nuclear weapons. Reprocessing of spent commercial-reactor nuclear fuel has not been permitted in the United States due to nonproliferation considerations. All other reprocessing nations have long had nuclear weapons from military-focused research reactor fuels except for Japan. Normally, with the fuel being changed every three years or so, about half of the ²³⁹Pu is 'burned' in the reactor, providing about one third of the total energy. It behaves like ²³⁵U and its fission releases a similar amount of energy. The higher the burnup, the more plutonium is present in the spent fuel, but the available fissile plutonium is lower. Typically about one percent of the used fuel discharged from a reactor is plutonium, and some two thirds of this is fissile (c. 50% ²³⁹Pu, 15% ²⁴¹Pu).

Metal fuel

Metal fuels have the advantage of a much higher heat conductivity than oxide fuels but cannot survive equally high temperatures. Metal fuels have a long history of use, stretching from the Clementine reactor in 1946 to many test and research reactors. Metal fuels have the potential for the highest fissile atom density. Metal fuels are normally alloyed, but some metal fuels have been made with pure uranium metal. Uranium alloys that have been used include uranium aluminum, uranium zirconium, uranium silicon, uranium molybdenum, uranium zirconium hydride (UZrH), and uranium zirconium carbonitride. Any of the aforementioned fuels can be made with plutonium and other actinides as part of a closed nuclear fuel cycle. Metal fuels have been used in light-water reactors and liquid metal fast breeder reactors, such as Experimental Breeder Reactor II.

TRIGA fuel

TRIGA fuel is used in TRIGA (Training, Research, Isotopes, General Atomics) reactors. The TRIGA reactor uses UZrH fuel, which has a prompt negative fuel temperature coefficient of reactivity, meaning that as the temperature of the core increases, the reactivity decreases—so it is highly unlikely for a meltdown to occur. Most cores that use this fuel are "high leakage" cores where the excess leaked neutrons can be utilized for research. That is, they can be used as a neutron source. TRIGA fuel was originally designed to use highly enriched uranium, however in 1978 the U.S. Department of Energy launched its Reduced Enrichment for Research Test Reactors program, which promoted reactor conversion to low-enriched uranium fuel. There are 35 TRIGA reactors in the US and an additional 35 in other countries.

Actinide fuel

In a fast-neutron reactor, the minor actinides produced by neutron capture of uranium and plutonium can be used as fuel. Metal actinide fuel is typically an alloy of zirconium, uranium, plutonium, and minor actinides. It can be made inherently safe as thermal expansion of the metal alloy will increase neutron leakage.

Molten plutonium

Molten plutonium, alloyed with other metals to lower its melting point and encapsulated in tantalum, was tested in two experimental reactors, LAMPRE I and LAMPRE II, at Los Alamos National Laboratory in the 1960s. LAMPRE experienced three separate fuel failures during operation.

Non-oxide ceramic fuels

Ceramic fuels other than oxides have the advantage of high heat conductivities and melting points, but they are more prone to swelling than oxide fuels and are not understood as well.

Uranium nitride

Uranium nitride is often the fuel of choice for reactor designs that NASA produces. One advantage is that uranium nitride has a better thermal conductivity than UO₂. Uranium nitride has a very high melting point. This fuel has the disadvantage that unless ¹⁵N was used (in place of the more common ¹⁴N), a large amount of ¹⁴C would be generated from the nitrogen by the (n,p) reaction.

As the nitrogen needed for such a fuel would be so expensive it is likely that the fuel would require pyroprocessing to enable recovery of the ¹⁵N. It is likely that if the fuel was processed and dissolved in nitric acid that the nitrogen enriched with ¹⁵N would be diluted with the common ¹⁴N. Fluoride volatility is a method of reprocessing that does not rely on nitric acid, but it has only been demonstrated in relatively small scale installations whereas the established PUREX process is used commercially for about a third of all spent nuclear fuel (the rest being largely subject to a "once through fuel cycle").

All nitrogen-fluoride compounds are volatile or gaseous at room temperature and could be fractionally distilled from the other gaseous products (including recovered uranium hexafluoride) to recover the initially used nitrogen. If the fuel could be processed in such a way as to ensure low contamination with non-radioactive carbon (not a common fission product and absent in nuclear reactors that don't use it as a moderator) then fluoride volatility could be used to separate the ¹⁴
C produced by producing carbon tetrafluoride. ¹⁴
C is proposed for use in particularly long lived low power nuclear batteries called diamond batteries.

Uranium carbide

Much of what is known about uranium carbide is in the form of pin-type fuel elements for liquid metal fast reactors during their intense study in the 1960s and 1970s. Recently there has been a revived interest in uranium carbide in the form of plate fuel and most notably, micro fuel particles (such as tristructural-isotropic particles).

The high thermal conductivity and high melting point makes uranium carbide an attractive fuel. In addition, because of the absence of oxygen in this fuel (during the course of irradiation, excess gas pressure can build from the formation of O₂ or other gases) as well as the ability to complement a ceramic coating (a ceramic-ceramic interface has structural and chemical advantages), uranium carbide could be the ideal fuel candidate for certain Generation IV reactors such as the gas-cooled fast reactor. While the neutron cross section of carbon is low, during years of burnup, the predominantly ¹²
C will undergo neutron capture to produce stable ¹³
C as well as radioactive ¹⁴
C. Unlike the ¹⁴
C produced by using uranium nitrate, the ¹⁴
C will make up only a small isotopic impurity in the overall carbon content and thus make the entirety of the carbon content unsuitable for non-nuclear uses but the ¹⁴
C concentration will be too low for use in nuclear batteries without enrichment. Nuclear graphite discharged from reactors where it was used as a moderator presents the same issue.

Liquid fuels

Liquid fuels contain dissolved nuclear fuel and have been shown to offer numerous operational advantages compared to traditional solid fuel approaches. Liquid-fuel reactors offer significant safety advantages due to their inherently stable "self-adjusting" reactor dynamics. This provides two major benefits: virtually eliminating the possibility of a runaway reactor meltdown, and providing an automatic load-following capability which is well suited to electricity generation and high-temperature industrial heat applications.

In some liquid core designs, the fuel can be drained rapidly into a passively safe dump-tank. This advantage was conclusively demonstrated repeatedly as part of a weekly shutdown procedure during the highly successful Molten-Salt Reactor Experiment from 1965 to 1969.

A liquid core is able to release xenon gas, which normally acts as a neutron absorber (¹³⁵
Xe is the strongest known neutron poison and is produced both directly and as a decay product of ¹³⁵
I as a fission product) and causes structural occlusions in solid fuel elements (leading to the early replacement of solid fuel rods with over 98% of the nuclear fuel unburned, including many long-lived actinides). In contrast, molten-salt reactors are capable of retaining the fuel mixture for significantly extended periods, which increases fuel efficiency dramatically and incinerates the vast majority of its own waste as part of the normal operational characteristics. A downside to letting the ¹³⁵
Xe escape instead of allowing it to capture neutrons converting it to the basically stable and chemically inert ¹³⁶
Xe, is that it will quickly decay to the highly chemically reactive, long lived radioactive ¹³⁵
Cs, which behaves similar to other alkali metals and can be taken up by organisms in their metabolism.

Molten salts

Molten salt fuels are mixtures of actinide salts (e.g. thorium/uranium fluoride/chloride) with other salts, used in liquid form above their typical melting points of several hundred degrees C. In some molten salt-fueled reactor designs, such as the liquid fluoride thorium reactor (LFTR), this fuel salt is also the coolant; in other designs, such as the stable salt reactor, the fuel salt is contained in fuel pins and the coolant is a separate, non-radioactive salt. There is a further category of molten salt-cooled reactors in which the fuel is not in molten salt form, but a molten salt is used for cooling.

Molten salt fuels were used in the LFTR known as the Molten Salt Reactor Experiment, as well as other liquid core reactor experiments. The liquid fuel for the molten salt reactor was a mixture of lithium, beryllium, thorium and uranium fluorides: LiF-BeF₂-ThF₄-UF₄ (72-16-12-0.4 mol%). It had a peak operating temperature of 705 °C in the experiment, but could have operated at much higher temperatures since the boiling point of the molten salt was in excess of 1400 °C.

Aqueous solutions of uranyl salts

The aqueous homogeneous reactors (AHRs) use a solution of uranyl sulfate or other uranium salt in water. Historically, AHRs have all been small research reactors, not large power reactors.

Liquid metals or alloys

The dual fluid reactor (DFR) has a variant DFR/m which works with eutectic liquid metal alloys, e.g. U-Cr or U-Fe.

Common physical forms

See also: Active fuel length

Uranium dioxide (UO₂) powder is compacted to cylindrical pellets and sintered at high temperatures to produce ceramic nuclear fuel pellets with a high density and well defined physical properties and chemical composition. A grinding process is used to achieve a uniform cylindrical geometry with narrow tolerances. Such fuel pellets are then stacked and filled into the metallic tubes. The metal used for the tubes depends on the design of the reactor. Stainless steel was used in the past, but most reactors now use a zirconium alloy which, in addition to being highly corrosion-resistant, has low neutron absorption. The tubes containing the fuel pellets are sealed: these tubes are called fuel rods. The finished fuel rods are grouped into fuel assemblies that are used to build up the core of a power reactor.

Cladding is the outer layer of the fuel rods, standing between the coolant and the nuclear fuel. It is made of a corrosion-resistant material with low absorption cross section for thermal neutrons, usually Zircaloy or steel in modern constructions, or magnesium with small amount of aluminium and other metals for the now-obsolete Magnox reactors. Cladding prevents radioactive fission fragments from escaping the fuel into the coolant and contaminating it. Besides the prevention of radioactive leaks this also serves to keep the coolant as non-corrosive as feasible and to prevent reactions between chemically aggressive fission products and the coolant. For example, the highly reactive alkali metal caesium which reacts strongly with water, producing hydrogen, and which is among the more common fission products.

• 
  Nuclear Regulatory Commission (NRC) photo of unirradiated (fresh) fuel pellets.
• 
  NRC photo of fresh fuel pellets ready for assembly.
• 
  NRC photo of fresh fuel assemblies being inspected.

PWR fuel assembly (also known as a fuel bundle) This fuel assembly is from a pressurized water reactor of the nuclear-powered passenger and cargo ship NS Savannah. Designed and built by the Babcock & Wilcox Company.

Pressurized water reactor fuel

Pressurized water reactor (PWR) fuel consists of cylindrical rods put into bundles. A uranium oxide ceramic is formed into pellets and inserted into Zircaloy tubes that are bundled together. The Zircaloy tubes are about 1 centimetre (0.4 in) in diameter, and the fuel cladding gap is filled with helium gas to improve heat conduction from the fuel to the cladding. There are about 179–264 fuel rods per fuel bundle and about 121 to 193 fuel bundles are loaded into a reactor core. Generally, the fuel bundles consist of fuel rods bundled 14×14 to 17×17. PWR fuel bundles are about 4 m (13 ft) long. In PWR fuel bundles, control rods are inserted through the top directly into the fuel bundle. The fuel bundles usually are enriched several percent in ²³⁵U. The uranium oxide is dried before inserting into the tubes to try to eliminate moisture in the ceramic fuel that can lead to corrosion and hydrogen embrittlement. The Zircaloy tubes are pressurized with helium to try to minimize pellet-cladding interaction which can lead to fuel rod failure over long periods.

Boiling water reactor fuel

In boiling water reactors (BWR), the fuel is similar to PWR fuel except that the bundles are "canned". That is, there is a thin tube surrounding each bundle. This is primarily done to prevent local density variations from affecting neutronics and thermal hydraulics of the reactor core. In modern BWR fuel bundles, there are either 91, 92, or 96 fuel rods per assembly depending on the manufacturer. A range between 368 assemblies for the smallest and 800 assemblies for the largest BWR in the U.S. form the reactor core. Each BWR fuel rod is backfilled with helium to a pressure of about 3 standard atmospheres (300 kPa).

CANDU fuel bundles, each about 50 cm long, 10 cm in diameter.

Canada deuterium uranium fuel

Canada deuterium uranium fuel (CANDU) fuel bundles are about 0.5 metres (20 in) long and 10 centimetres (4 in) in diameter. They consist of sintered (UO₂) pellets in zirconium alloy tubes, welded to zirconium alloy end plates. Each bundle weighs roughly 20 kilograms (44 lb), and a typical core loading is on the order of 4500–6500 bundles, depending on the design. Modern types typically have 37 identical fuel pins radially arranged about the long axis of the bundle, but in the past several different configurations and numbers of pins have been used. The CANFLEX bundle has 43 fuel elements, with two element sizes. It is also about 10 cm (4 inches) in diameter, 0.5 m (20 in) long and weighs about 20 kg (44 lb) and replaces the 37-pin standard bundle. It has been designed specifically to increase fuel performance by utilizing two different pin diameters. Current CANDU designs do not need enriched uranium to achieve criticality (due to the lower neutron absorption in their heavy water moderator compared to light water), however, some newer concepts call for low enrichment to help reduce the size of the reactors. The Atucha nuclear power plant in Argentina, a similar design to the CANDU but built by German KWU was originally designed for non-enriched fuel but since switched to slightly enriched fuel with a ²³⁵
U content about 0.1 percentage points higher than in natural uranium.

Less-common fuel forms

Various other nuclear fuel forms find use in specific applications, but lack the widespread use of those found in BWRs, PWRs, and CANDU power plants. Many of these fuel forms are only found in research reactors, or have military applications.

A Magnox fuel rod

Magnox fuel

Main article: Magnox

Magnox (magnesium non-oxidising) reactors are pressurised, carbon dioxide–cooled, graphite-moderated reactors using natural uranium (i.e. unenriched) as fuel and Magnox alloy as fuel cladding. Working pressure varies from 6.9 to 19.35 bars (100.1 to 280.6 psi) for the steel pressure vessels, and the two reinforced concrete designs operated at 24.8 and 27 bars (24.5 and 26.6 atm). Magnox alloy consists mainly of magnesium with small amounts of aluminium and other metals—used in cladding unenriched uranium metal fuel with a non-oxidising covering to contain fission products. This material has the advantage of a low neutron capture cross-section, but has two major disadvantages:

• It limits the maximum temperature, and hence the thermal efficiency, of the plant.
• It reacts with water, preventing long-term storage of spent fuel under water - such as in a spent fuel pool.

Magnox fuel incorporated cooling fins to provide maximum heat transfer despite low operating temperatures, making it expensive to produce. While the use of uranium metal rather than oxide made nuclear reprocessing more straightforward and therefore cheaper, the need to reprocess fuel a short time after removal from the reactor meant that the fission product hazard was severe. Expensive remote handling facilities were required to address this issue.

Tristructural-isotropic fuel

0.845 mm TRISO fuel particle which has been cracked, showing multiple layers that are coating the spherical kernel

Tristructural-isotropic (TRISO) fuel is a type of micro-particle fuel. A particle consists of a kernel of UO_X fuel (sometimes UC or UCO), which has been coated with four layers of three isotropic materials deposited through fluidized chemical vapor deposition (FCVD). The four layers are a porous buffer layer made of carbon that absorbs fission product recoils, followed by a dense inner layer of protective pyrolytic carbon (PyC), followed by a ceramic layer of SiC to retain fission products at elevated temperatures and to give the TRISO particle more structural integrity, followed by a dense outer layer of PyC. TRISO particles are then encapsulated into cylindrical or spherical graphite pellets. TRISO fuel particles are designed not to crack due to the stresses from processes (such as differential thermal expansion or fission gas pressure) at temperatures up to 1600 °C, and therefore can contain the fuel in the worst of accident scenarios in a properly designed reactor. Two such reactor designs are the prismatic-block gas-cooled reactor (such as the GT-MHR) and the pebble-bed reactor (PBR). Both of these reactor designs are high temperature gas reactors (HTGRs). These are also the basic reactor designs of very-high-temperature reactors (VHTRs), one of the six classes of reactor designs in the Generation IV initiative that is attempting to reach even higher HTGR outlet temperatures.

TRISO fuel particles were originally developed in the United Kingdom as part of the Dragon reactor project. The inclusion of the SiC as diffusion barrier was first suggested by D. T. Livey. The first nuclear reactor to use TRISO fuels was the Dragon reactor and the first powerplant was the THTR-300. Currently, TRISO fuel compacts are being used in some experimental reactors, such as the HTR-10 in China and the high-temperature engineering test reactor in Japan. In the United States, spherical fuel elements utilizing a TRISO particle with a UO₂ and UC solid solution kernel are being used in the Xe-100, and Kairos Power is developing a 140 MWE nuclear reactor that uses TRISO.

QUADRISO fuel

QUADRISO Particle

In QUADRISO particles a burnable neutron poison (europium oxide or erbium oxide or carbide) layer surrounds the fuel kernel of ordinary TRISO particles to better manage the excess of reactivity. If the core is equipped both with TRISO and QUADRISO fuels, at beginning of life neutrons do not reach the fuel of the QUADRISO particles because they are stopped by the burnable poison. During reactor operation, neutron irradiation of the poison causes it to "burn up" or progressively transmute to non-poison isotopes, depleting this poison effect and leaving progressively more neutrons available for sustaining the chain-reaction. This mechanism compensates for the accumulation of undesirable neutron poisons which are an unavoidable part of the fission products, as well as normal fissile fuel "burn up" or depletion. In the generalized QUADRISO fuel concept the poison can eventually be mixed with the fuel kernel or the outer pyrocarbon. The QUADRISO concept was conceived at Argonne National Laboratory.

RBMK reactor fuel rod holder 1 – distancing armature; 2 – fuel rods shell; 3 – fuel tablets.

RBMK fuel

RBMK reactor fuel was used in Soviet-designed and built RBMK-type reactors. This is a low-enriched uranium oxide fuel. The fuel elements in an RBMK are 3 m long each, and two of these sit back-to-back on each fuel channel, pressure tube. Reprocessed uranium from Russian VVER reactor spent fuel is used to fabricate RBMK fuel. Following the Chernobyl accident, the enrichment of fuel was changed from 2.0% to 2.4%, to compensate for control rod modifications and the introduction of additional absorbers.

CerMet fuel

CerMet fuel consists of ceramic fuel particles (usually uranium oxide) embedded in a metal matrix. It is hypothesized that this type of fuel is what is used in United States Navy reactors. This fuel has high heat transport characteristics and can withstand a large amount of expansion.

Plate-type fuel

ATR Core The Advanced Test Reactor at Idaho National Laboratory uses plate-type fuel in a clover leaf arrangement. The blue glow around the core is known as Cherenkov radiation.

Plate-type fuel has fallen out of favor over the years. Plate-type fuel is commonly composed of enriched uranium sandwiched between metal cladding. Plate-type fuel is used in several research reactors where a high neutron flux is desired, for uses such as material irradiation studies or isotope production, without the high temperatures seen in ceramic, cylindrical fuel. It is currently used in the Advanced Test Reactor (ATR) at Idaho National Laboratory, and the nuclear research reactor at the University of Massachusetts Lowell Radiation Laboratory.

Sodium-bonded fuel

Sodium-bonded fuel consists of fuel that has liquid sodium in the gap between the fuel slug (or pellet) and the cladding. This fuel type is often used for sodium-cooled liquid metal fast reactors. It has been used in EBR-I, EBR-II, and the FFTF. The fuel slug may be metallic or ceramic. The sodium bonding is used to reduce the temperature of the fuel.

Accident tolerant fuels

Accident tolerant fuels (ATF) are a series of new nuclear fuel concepts, researched in order to improve fuel performance under accident conditions, such as loss-of-coolant accident (LOCA) or reaction-initiated accidents (RIA). These concerns became more prominent after the Fukushima Daiichi nuclear disaster in Japan, in particular regarding light-water reactor (LWR) fuels performance under accident conditions.

Neutronics analyses were performed for the application of the new fuel-cladding material systems for various types of ATF materials.

The aim of the research is to develop nuclear fuels that can tolerate loss of active cooling for a considerably longer period than the existing fuel designs and prevent or delay the release of radionuclides during an accident. This research is focused on reconsidering the design of fuel pellets and cladding, as well as the interactions between the two.

Spent nuclear fuel

Main article: Spent nuclear fuel

Used nuclear fuel is a complex mixture of the fission products, uranium, plutonium, and the transplutonium metals. In fuel which has been used at high temperature in power reactors it is common for the fuel to be heterogeneous; often the fuel will contain nanoparticles of platinum group metals such as palladium. Also the fuel may well have cracked, swollen, and been heated close to its melting point. Despite the fact that the used fuel can be cracked, it is very insoluble in water, and is able to retain the vast majority of the actinides and fission products within the uranium dioxide crystal lattice. The radiation hazard from spent nuclear fuel declines as its radioactive components decay, but remains high for many years. For example 10 years after removal from a reactor, the surface dose rate for a typical spent fuel assembly still exceeds 10,000 rem/hour, resulting in a fatal dose in just minutes.

Oxide fuel under accident conditions

Main article: Behavior of nuclear fuel during a reactor accident

Two main modes of release exist, the fission products can be vaporised or small particles of the fuel can be dispersed.

Fuel behavior and post-irradiation examination

Main article: Post Irradiation Examination

Post-Irradiation Examination (PIE) is the study of used nuclear materials such as nuclear fuel. It has several purposes. It is known that by examination of used fuel that the failure modes which occur during normal use (and the manner in which the fuel will behave during an accident) can be studied. In addition information is gained which enables the users of fuel to assure themselves of its quality and it also assists in the development of new fuels. After major accidents the core (or what is left of it) is normally subject to PIE to find out what happened. One site where PIE is done is the ITU which is the EU centre for the study of highly radioactive materials.

Materials in a high-radiation environment (such as a reactor) can undergo unique behaviors such as swelling and non-thermal creep. If there are nuclear reactions within the material (such as what happens in the fuel), the stoichiometry will also change slowly over time. These behaviors can lead to new material properties, cracking, and fission gas release.

The thermal conductivity of uranium dioxide is low; it is affected by porosity and burn-up. The burn-up results in fission products being dissolved in the lattice (such as lanthanides), the precipitation of fission products such as palladium, the formation of fission gas bubbles due to fission products such as xenon and krypton and radiation damage of the lattice. The low thermal conductivity can lead to overheating of the center part of the pellets during use. The porosity results in a decrease in both the thermal conductivity of the fuel and the swelling which occurs during use.

According to the International Nuclear Safety Center the thermal conductivity of uranium dioxide can be predicted under different conditions by a series of equations.

The bulk density of the fuel can be related to the thermal conductivity.

Where ρ is the bulk density of the fuel and ρ_td is the theoretical density of the uranium dioxide.

Then the thermal conductivity of the porous phase (K_f) is related to the conductivity of the perfect phase (K_o, no porosity) by the following equation. Note that s is a term for the shape factor of the holes.

K_f = K_o(1 − p/1 + (s − 1)p)

Rather than measuring the thermal conductivity using the traditional methods such as Lees' disk, the Forbes' method, or Searle's bar, it is common to use Laser Flash Analysis where a small disc of fuel is placed in a furnace. After being heated to the required temperature one side of the disc is illuminated with a laser pulse, the time required for the heat wave to flow through the disc, the density of the disc, and the thickness of the disk can then be used to calculate and determine the thermal conductivity.

λ = ρC_pα

• λ thermal conductivity
• ρ density
• C_p heat capacity
• α thermal diffusivity

If t_1/2 is defined as the time required for the non illuminated surface to experience half its final temperature rise then.

α = 0.1388 L²/t_1/2

• L is the thickness of the disc

For details see K. Shinzato and T. Baba (2001).

Radioisotope decay fuels

Radioisotope battery

Main article: Atomic battery

An atomic battery (also called a nuclear battery or radioisotope battery) is a device which uses the radioactive decay to generate electricity. These systems use radioisotopes that produce low energy beta particles or sometimes alpha particles of varying energies. Low energy beta particles are needed to prevent the production of high energy penetrating bremsstrahlung radiation that would require heavy shielding. Radioisotopes such as plutonium-238, curium-242, curium-244 and strontium-90 have been used. Tritium, nickel-63, promethium-147, and technetium-99 have been tested.

There are two main categories of atomic batteries: thermal and non-thermal. The non-thermal atomic batteries, which have many different designs, exploit charged alpha and beta particles. These designs include the direct charging generators, betavoltaics, the optoelectric nuclear battery, and the radioisotope piezoelectric generator. The thermal atomic batteries on the other hand, convert the heat from the radioactive decay to electricity. These designs include thermionic converter, thermophotovoltaic cells, alkali-metal thermal to electric converter, and the most common design, the radioisotope thermoelectric generator.

Radioisotope thermoelectric generator

Inspection of Cassini spacecraft RTGs before launch

Main article: Radioisotope thermoelectric generator

A radioisotope thermoelectric generator (RTG) is a simple electrical generator which converts heat into electricity from a radioisotope using an array of thermocouples.

²³⁸
Pu
has become the most widely used fuel for RTGs, in the form of plutonium dioxide. It has a half-life of 87.7 years, reasonable energy density, and exceptionally low gamma and neutron radiation levels. Some Russian terrestrial RTGs have used ⁹⁰
Sr
; this isotope has a shorter half-life and a much lower energy density, but is cheaper. Early RTGs, first built in 1958 by the U.S. Atomic Energy Commission, have used ²¹⁰
Po
. This fuel provides phenomenally huge energy density, (a single gram of polonium-210 generates 140 watts thermal) but has limited use because of its very short half-life and gamma production, and has been phased out of use for this application.

Photo of a disassembled RHU

Radioisotope heater unit (RHU)

Main article: Radioisotope heater unit

A radioisotope heater unit (RHU) typically provides about 1 watt of heat each, derived from the decay of a few grams of plutonium-238. This heat is given off continuously for several decades.

Their function is to provide highly localised heating of sensitive equipment (such as electronics in outer space). The Cassini–Huygens orbiter to Saturn contains 82 of these units (in addition to its 3 main RTGs for power generation). The Huygens probe to Titan contains 35 devices.

Fusion fuels

Main article: Fusion power § Fuels

Fusion fuels are fuels to use in hypothetical Fusion power reactors. They include deuterium (²H) and tritium (³H) as well as helium-3 (³He). Many other elements can be fused together, but the larger electrical charge of their nuclei means that much higher temperatures are required. Only the fusion of the lightest elements is seriously considered as a future energy source. Fusion of the lightest atom, ¹H hydrogen, as is done in the Sun and other stars, has also not been considered practical on Earth. Although the energy density of fusion fuel is even higher than fission fuel, and fusion reactions sustained for a few minutes have been achieved, utilizing fusion fuel as a net energy source remains only a theoretical possibility.

First-generation fusion fuel

Deuterium and tritium are both considered first-generation fusion fuels; they are the easiest to fuse, because the electrical charge on their nuclei is the lowest of all elements. The three most commonly cited nuclear reactions that could be used to generate energy are:

²H + ³H → n (14.07 MeV) + ⁴He (3.52 MeV)

²H + ²H → n (2.45 MeV) + ³He (0.82 MeV)

²H + ²H → p (3.02 MeV) + ³H (1.01 MeV)

Second-generation fusion fuel

Second-generation fuels require either higher confinement temperatures or longer confinement time than those required of first-generation fusion fuels, but generate fewer neutrons. Neutrons are an unwanted byproduct of fusion reactions in an energy generation context, because they are absorbed by the walls of a fusion chamber, making them radioactive. They cannot be confined by magnetic fields, because they are not electrically charged. This group consists of deuterium and helium-3. The products are all charged particles, but there may be significant side reactions leading to the production of neutrons.

²H + ³He → p (14.68 MeV) + ⁴He (3.67 MeV)

Third-generation fusion fuel

Main article: Aneutronic fusion

Third-generation fusion fuels produce only charged particles in the primary reactions, and side reactions are relatively unimportant. Since a very small amount of neutrons is produced, there would be little induced radioactivity in the walls of the fusion chamber. This is often seen as the end goal of fusion research. ³He has the highest Maxwellian reactivity of any 3rd generation fusion fuel. However, there are no significant natural sources of this substance on Earth.

³He + ³He → 2 p + ⁴He (12.86 MeV)

Another potential aneutronic fusion reaction is the proton-boron reaction:

p + ¹¹B → 3 ⁴He (8.7 MeV)

Under reasonable assumptions, side reactions will result in about 0.1% of the fusion power being carried by neutrons. With 123 keV, the optimum temperature for this reaction is nearly ten times higher than that for the pure hydrogen reactions, the energy confinement must be 500 times better than that required for the D-T reaction, and the power density will be 2500 times lower than for D-T.

See also

• Fissile material
• Global Nuclear Energy Partnership
• Integrated Nuclear Fuel Cycle Information System
• Lists of nuclear disasters and radioactive incidents
• Nuclear fuel bank
• Nuclear fuel cycle
• Reprocessed uranium
• Uranium market

External links

• Plutonium Fuel Fabrication by Argonne National Laboratory on YouTube

PWR fuel

• "NEI fuel schematic". Archived from the original on 2004-10-22. Retrieved 2005-12-14.
• "Picture of a PWR fuel assembly". Archived from the original on 2015-04-23. Retrieved 2005-12-14.
• Picture showing handling of a PWR bundle
• "Mitsubishi nuclear fuel Co". Archived from the original on 2012-02-24. Retrieved 2005-12-14.

BWR fuel

• "Picture of a "canned" BWR assembly". Archived from the original on 2006-08-28. Retrieved 2005-12-14.
• Physical description of LWR fuel
• Links to BWR photos from the nuclear tourist webpage

CANDU fuel

• CANDU Fuel pictures and FAQ
• Basics on CANDU design
• The Evolution of CANDU Fuel Cycles and their Potential Contribution to World Peace
• "CANDU Fuel-Management Course" (PDF). Archived from the original (PDF) on 2006-03-15. Retrieved 2005-12-17.
• CANDU Fuel and Reactor Specifics (Nuclear Tourist)
• Candu Fuel Rods and Bundles

TRISO fuel

• Alameri, Saeed A.; Alrwashdeh, Mohammad (2021). "Preliminary three-dimensional neutronic analysis of IFBA coated TRISO fuel particles in prismatic-core advanced high temperature reactor". Annals of Nuclear Energy. 163. doi:10.1016/j.anucene.2021.108551.
• Alrwashdeh, Mohammad; Alameri, Saeed A.; Alkaabi, Ahmed K. (2020). "Preliminary Study of a Prismatic-Core Advanced High-Temperature Reactor Fuel Using Homogenization Double-Heterogeneous Method". Nuclear Science and Engineering. 194 (2): 163–167. Bibcode:2020NSE...194..163A. doi:10.1080/00295639.2019.1672511. S2CID 209983934.
• TRISO fuel descripción
• Non-Destructive Examination of SiC Nuclear Fuel Shell using X-Ray Fluorescence Microtomography Technique
• GT-MHR fuel compact process Archived 2006-03-06 at the Wayback Machine
• Description of TRISO fuel for "pebbles"
• LANL webpage showing various stages of TRISO fuel production
• Method to calculate the temperature profile in TRISO fuel Archived 2016-04-15 at the Wayback Machine

QUADRISO fuel

• Conceptual Design of QUADRISO Fuel

CERMET fuel

• "A Review of Fifty Years of Space Nuclear Fuel Development Programs" (PDF). Archived from the original (PDF) on 2005-12-30. Retrieved 2005-12-14.
• Thoria-based Cermet Nuclear Fuel: Sintered Microsphere Fabrication by Spray Drying
• "The Use of Molybdenum-Based Ceramic-Metal (CerMet) Fuel for the Actinide Management in LWRs" (PDF). Archived from the original (PDF) on 2006-03-19. Retrieved 2005-12-14.

Plate type fuel

• https://pubs.aip.org/aip/adv/article/9/7/075112/22584/Reactor-Monte-Carlo-RMC-model-validation-and
• List of reactors at INL and picture of ATR core
• ATR plate fuel

TRIGA fuel

• "General Atomics TRIGA fuel website". Archived from the original on 2005-12-23. Retrieved 2005-12-14.

Fusion fuel

• Advanced fusion fuels presentation Archived 2016-04-15 at the Wayback Machine